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eConnosseur offer Software Solutions to our global clients by leveraging process, domain and people management expertise. At econnoisseur we have built our organization around managing risk for our clients through a scalable, cost-effective and predictable delivery platform.For More Informations Please Contact: gurpreet.kaur@econn.in(www.econnoisseur.com/econnparsing)
TOC vs SOC/FOC/DOC?
I work in a lab using a TOC analyser. When I do a Dissolved Organic Carbon run, it is guaranteed to have more DOC than the TOC? Why is the case and how can I stop this from occuring? (Repeating the samples continueously is really boring)
Ok we have already thought of the things that you are suggesting ie. ran filtered blanks, checked the pH (neutral pH 5 ~ 8). Do you think that running the sample acidified will solve my problems?
I would need to see the results of all the blank runs to make any further comment. The blanks should match the pH of the samples and should be run side by side with the samples using the same filter lot and using the same technician and analyst. The samples should be run blank-standard-blank-sample-blank. Collect data on about 10-20 samples in this way with a separate blank for each sample.
There can be several causes for this that you need to check.
1. The level of solids in the unfiltered samples is such that it impacts the measurement.
2. The filters you are using have not been cleaned properly and material from them is being added to the DOC.
3. Your sample is caustic or acid and is dissolving some of the filter material.
Try running a series of standards and blanks, both TOC and DOC. Adjust the samples to a caustic and acidic pH. My guess is that you are measuring material from your filters. You may have to double your cleanings or switch brands. Another option is to check the total and soluble COD. You should see the same pattern if it is the filters. And of couse, it could be a combination of these problems.
Funding Update
The Malik lab is looking at evolutionary studies of genetic conflict to gain insight into their mechanisms and consequences. To this end, they are studying centromeres, mobile genetic elements and rapidly evolving proteins in Drosophila.
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